My research makes three main contributions. It intercedes in the debate on social capital in American society from a historical perspective. Addressing a dearth of historical analyses of social capital formation, it also provides a major assessment of social networks within the most dynamic popular movement of the first half of the nineteenth century. Whereas popular supporters and critics of the social capital thesis often align according to their philosophical embrace of communitarianism or individualism, I show that these categories are historically inseparable, as Euro- American settlers built societies in the West and reaped the benefits of individual and collective social capital to lay the foundation for a middle-class order. Second, my approach bridges an impasse in the historiographical debate on the Second Great Awakening: that is, whether popular evangelicalism democratized American culture. Scholars on one side of the debate have marshaled evidence of anti-elite ideology while others have focused on divisions according to race, class, and gender. Through Methodism I argue that evangelical networks allowed white middling settlers to weaken existing social hierarchies at the very time that they built new ones. Finally, my interpretation centers religion in the search for the origins of the southern middle class, a field currently among the most energetic in southern history. Rather than democratization or its opposite, the Methodists laid the foundation for the emergence of a nineteenth-century middle class of settlers who molded southern and western society according to their principles.